Optimization of Epoxidation Palm-Based Oleic Acid to Produce Polyols

نویسندگان

چکیده

Optimization of epoxidation by using response surface methodology (RSM) based on three-level three-factorial central composite design (CCD) was used. Response percentage relative oxirane content (%RCO) studied to determine the optimum reaction condition for production polyols. The predicted value model (85 %) excellent in accordance experimental (81 %). All parameters (temperature, molar ratio formic acid oleic and hydrogen peroxide acid) were significant influencing course (p < 0.05). interaction between all is also highly with p 0.0001. Optimum conditions obtained from RSM as follows: temperature 318 K, 1.64:1 2:1. palm carried out situ performic acid. FTIR analysis showed formation epoxy functional groups at wavelength 1340 cm-1. This epoxide group used produce polyols hydroxylation process detected 816 cm-1

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ژورنال

عنوان ژورنال: Chemistry and Chemical Technology

سال: 2022

ISSN: ['1996-4196']

DOI: https://doi.org/10.23939/chcht16.01.066